HC15N, v2 = 1
Hydrogen Cyanide, 15N isotopolog, v2 = 1
Species tag 028507
Version2*
Date of EntryDec. 2017
ContributorH. S. P. Müller

The first entry from Aug. 2005 has been revised considerably. Additional infrared data involving states v2 = 2 and 3 as well as v3 = 1 and v1 = 1 were included along with additional pure rotational data pertaining to v2 = 2 and 3 as well as v3 = 1. All these data were subjected to one combined fit.
Pure rotational transition frequencies for v = 0 and v2 = 1 were taken from
(1) U. Fuchs, S. Brünken, G. W. Fuchs, S. Thorwirth, V. Ahrens, F. Lewen, S. Urban, T. Giesen, G. Winnewisser, 2004, Z. Naturforsch., 59a, 861.
Additional v = 0 frequencies were publised in
(2) G. Cazzoli, C. Puzzarini, and J. Gauss, 2005, Astrophys. J. Suppl. Ser. 159, 181.
The v2 = 1 direct-l-type transitions were reported by
(3) M. Winnewisser and J. Vogt, 1978, Z. Naturforsch., 33a, 1323.
Higher vibrational state rotational data were taken from
(4) J. Preusser and A. G. Maki, 1993, J. Mol. Spectrosc. 162, 484.
Finally, extensive infrared data come from
(5) A. G. Maki, G. C. Mellau, S. Klee, M. Winnewisser, and W. Quapp, 2000, J. Mol. Spectrosc. 202, 67.
The main improvement occured in the partition function, which is essentially converged at 300 K and probably still good up to about 500 K. The rotational part is well converged up to 1000 K. The frequencies are also better at higher values of J. Predictions should be reliable throughout, but should be viewed with some caution above 3 THz for ΔJ = 1 transitions and above 0.2 THz for ΔJ = 0 transitions.
The dipole moment was assumed to agree with that of the main isotopic species, see e027503.cat.
The partition function takes into account all vibrational states used in the fit.

Lines Listed214
Frequency / GHz< 6343
Max. J75
log STR0-18.0
log STR1-18.0
Isotope Corr.-2.444
Egy / (cm–1)712.465
 µa / D2.9420
 µb / D 
 µc / D 
 A 
 B43129.732
 C 
 Q(1000.)1138.9818
 Q(500.0)319.8255
 Q(300.0)155.7320
 Q(225.0)111.6669
 Q(150.0)73.1505
 Q(75.00)36.6598
 Q(37.50)18.4981
 Q(18.75)9.4210
 Q(9.375)4.8887
 Q(5.000)2.7846
 Q(2.725)1.7128
detected in ISM/CSMno


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schloeder