H13CN, v3 = 1
Hydrogen Cyanide, 13C isotopic species, v3 = 1
Species tag 028522
Version1*
Date of EntryNov 2014
ContributorH. S. P. Müller

Rovibrational and, as far as published, rotational data involving states v2 = 0 to 3 as well as v3 = 1 and v1 = 1 were used in the fit.
Data for v = 0 and v2 = 1, including direct-l-type transitions up to J = 35 for v2 = 1, were reported in
(1) U. Fuchs, S. Brünken, G. W. Fuchs, S. Thorwirth, V. Ahrens, F. Lewen, S. Urban, T. Giesen, and G. Winnewisser, 2004, Z. Naturforsch. 59a, 861.
Additional v = 0 data come from
(2) G. Cazzoli and C. Puzzarini, 2005, J. Mol. Spectrosc. 233, 280;
and from
(3) F. Maiwald, F. Lewen, V. Ahrens, M. Beaky, R. Gendriesch, A. N. Koroliev, A. A. Negirev, D. G. Paveljev, B. Vohwinkel, and G. Winnewisser 2000, J. Mol. Spectrosc. 202, 166.
Further direct-l-type transitions 6 ≤ J ≤ 15 were published in
(4) M. Winnewisser and J. Vogt, 1978, Z. Naturforsch. 33a, 1323.
The 2nd entry also employs v2 = 2 and 3 rotational data from
(5) J. Preusser and A. G. Maki, 1993, J. Mol. Spectrosc. 162, 484.
The fit also takes into account the very extensive infrared data between the various vibrational states from
(6) A. G. Maki, G. C. Mellau, S. Klee, M. Winnewisser, and W. Quapp, 2000, J. Mol. Spectrosc. 202, 67.
The partition function is essentially converged at 300 K and probably still good up to about 500 K. The rotational part is well converged up to 1000 K. Even though no pure rotational transition frequencies have been published, predictions with calculated uncertainties below 6 THz should be viewed only with slight caution. Greater caution is advised at higher frequencies.
The dipole moment was assumed to be the same as for the main isotopic species; see e027509.cat.
Note: the spin multiplicity gI of 3 for the 14N nucleus has been considered in the calculation of the partition function and the upper state degeneracy gup.
The partition function takes into account all vibrational states used in the fit.

Lines Listed80
Frequency / GHz< 6692
Max. J80
log STR0-23.0
log STR1-23.0
Isotope Corr.-1.955
Egy / (cm–1)2063.05
 µa / D2.9805
 µb / D 
 µc / D 
 A 
 B42877.73
 C 
 Q(1000.)3427.9692
 Q(500.0)960.4179
 Q(300.0)466.4373
 Q(225.0)334.1323
 Q(150.0)218.7542
 Q(75.00)109.6199
 Q(37.50)55.3144
 Q(18.75)28.1733
 Q(9.375)14.6213
 Q(5.000)8.3302
 Q(2.725)5.1261
detected in ISM/CSMnot yet


Database maintained by Holger S. P. Müller and Sven Thorwirth, programming by D. Roth and F. Schloeder