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Universität zu Köln
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Mathematisch-Naturwissenschaftliche Fakultät
Fachgruppe Physik

I. Physikalisches Institut

Research Projects

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C2H5OH  –  ethanol

Investigators

  • lewen
  • hspm

Description

Ethanol (CH3CH2OH) is a heavier homologue of the ubiquitous methanol (CH3OH) and an isomer of dimethyl ether. Ethanol is abundant enough in warmer and denser parts of star-forming regions that minor isotopologues may be observable, especially those involving one 13C or one D. Relative abundances of isotopologues, of isomers, and of homologues may help to constrain their chemical formation pathways. ...more

Methods

Absorption Rotational Spectroscopy
Rotational spectroscopy is a key method to investigate molecules, radicals and ions. These species are capable of motions, in particular molecular rotation. If a permanent or induced dipole moment is existent, the species is called transient and the underlying energy states are quantized and accessible for electromagnetic waves. The energy distances between the rotational levels are such, that mostly the transition lines are in cm- (up to 30 GHz) and mm- (up to 300 GHz) wavelength range of the electromagnetic spectrum. Since the energies necessary to excite the rotational states are low, the typical temperatures in the ISM are sufficiently high for exiting these states (T = 5 K to > 100 K). The line frequencies of the transitions can be measured with great accuracy; this in turn gives precise molecular constants, which allows calculating reliable predictions of new molecular lines which helps to indentify new molecular species in space. Such line lists and constants for many species are available in our Cologne Database for Molecular Spectroscopy (www. CDMS.de).
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Instruments

MIDAS-COINS
With its exceptionally long absorption path, MIDAS-COINS is enhancing our sensitivity in the millimeter range since 2010.
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The Cologne Terahertz Spectrometer
In Cologne, high resolution, broadband scanning spectroscopy with microwave accuracy has been extended into the terahertz region (λ < 0.3 mm) by stabilization of continuously tunable backward wave oscillators (BWOs) from Russian fabrication. Precise measurements have been performed up to 1.3 THz, a frequency which has never been reached before directly using microwave techniques, i.e. without generation of harmonics.
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Recent Results

Ethanol species with one 13C:

We characterized the two 13C isotopic species of ethanol employing isotopically enriched samples. Spectra were measured between 80 and 800 GHz. The analyses were limited to quantum numbers for which the anti conformer can be treated as separate species. The accurate data have been published by Bouchez et al.

Both 13C isotopologues were identified unambiguously later in an investigation of alkanols and alkanethiols in Sagittarius B2(N2).

Example spectra for 13C1 ethanol of (a) a single line 121,12 – 110,11 and (b) a line showing asymmetric torsional splitting 126,7 – 125,8.
Ethanol-2-13C spectral recording near 89.1 GHz. Total integration time was 40 ms per point, the step size 25 kHz. The scanning time for this spectrum was about 15 minutes, no baseline correction has been carried out yet.
Ethanol species with one D:

Subsequently, we investigated the three isotopologues of singly deuterated ethanol (C2H5OD, CH3CHDOH and CH2DCH2OH). Initial calculations were based on the results of J. P. Culot, who published measurements of deuterated ethanol between 26 and 58 GHz in 1969. From these data, we predicted transitions for higher frequencies with H. M. Pickett's programs SPFIT and SPCAT. Absorption lines have been measured between 38 and 129 GHz using MIDAS-COINS, a similar spectrometer was used to cover 360 to 500 GHz. The region from 210 to 365 GHz was covered with a backward wave oscillator spectrometer. Our new data were published by Walters et al.

Publications

External Links

Acknowledgments

  • The investigations have been funded by the Deutsche Forschungsgemeinschaft (DFG) within the Collaborative Research Centre 956 "Conditions and Impact of Star Formation", project B3.
  • Travel for A.B. and A.W. was partially supported by the French CNRS program “Physique et Chimie du Milieu Interstellaire” (PCMI).