On the Detection of HCNO Isomers in the Interstellar Medium

Isocyanic acid, HNCO, was among the very early molecules to be detected in space. The 40,4 – 30,3 transition at 3.4 mm was the first one to be detected in the Galactic center source Sgr B2(OH) by
L. E. Snyder and D. Buhl,
Interstellar Isocyanic Acid
Astrophys. J. 177, (1972), 619.
The 10,1 – 00,0 transition was detected subsequently by
D. Buhl, L. E. Snyder, and J. Edrich,
An Interstellar Emission Line from Isocyanic Acid at 1.4 Centimeters
Astrophys. J. 177, (1972), 625.

The molecule is also abundant in dark clouds, such as TMC-1, where the molecule was detected by
R. L. Brown,
Isocyanic Acid in the Taurus Molecular Cloud 1
Astrophys. J. 248, (1981), L119.

It was also found in three translucent clouds (CB 17 CB 24, and CB 228):
B. E. Turner, R. Terzieva, and E. Herbst,
The Physics and Chemistry of Small Translucent Molecular Clouds. XII. More Complex Species Explainable by Gas-Phase Processes
Astrophys. J. 518, 699–732 (1999).

F. Wyrowski, P. Schilke, and C. M. Walmsley
not only reported on
Vibrationally Excited HC3N toward Hot Cores
Astron. Astrophys. 341, 882–895 (1999);
but also on the detection of vibrationally excited HNCO with the IRAM 30 m telescope in Gal 10.47+0.03, which is also known as W31C (or part of the same cloud complex). Several J = 5 – 4 and 7 – 6 transitions pertaining to the ground state and the three lowest excited vibrational states were detected near 110 and 154 GHz.

A. Coutens, J. K. Jørgensen, M. H. D. van der Wiel, H. S. P. Müller, J. M. Lykke, P. Bjerkeli, T. L. Bourke, H. Calcutt, M. N. Drozdovskaya, C. Favre, E. C. Fayolle, R. T. Garrod, S. K. Jacobsen, N. F. W. Ligterink, K. I. Öberg, M. V. Persson, E. F. van Dishoeck, and S. F. Wampfler
reported on
The ALMA-PILS Survey: First Detections of Deuterated Formamide and Deuterated Isocyanic Acid in the Interstellar Medium
Astron. Astrophys. 590, Art. No. L6 (2016).
Carrying out a line survey toward IRAS 16293-2422 between 329 and 363 GHz, a deuteration degree of about one percent was derived for source B assuming a 12C/13C ratio of 68 because lines of the main isotopolog are frequently affected by optical depth effects. The letter is also the first unambiguous detection of the 13C species whose lines are frequently overlapped by those of the main species at much lower frequencies.

The detection of fulminic acid, HCNO, the second isomer, has been reported by
N. Marcelino, J. Cernicharo, B. Tercero, and E. Roueff,
Discovery of Fulminic Acid, HCNO, in Dark Clouds
Astrophys. J. 690, (2009), L27.
The IRAM 30 m telescope has been employed to detect the J = 4 – 3 and 5 – 4 transitions in B1 and toward the protostar position of L1527. The former transition was also detected toward the carbon chain peak of L1527, L1544, and L183. Interestingly, it was searched for, but not found toward the cyanopolyyne peak of the O-deficient dark cloud TMC-1. Moreover, it was not found in Orion KL. The HNCO isomer was found in all these sources.

Obviously, the detection of three transitions would have been more convincing. However, there are several reasons why the detection probably can be viewed as quite secure: the number of lines is quite low in dark clouds, in particular that of U-lines; the rotational temperatures in the two sources, in which both transitions have been detected, is identical within error bars with that of HNCO; the HNCO/HCNO ratio in the sources in which HCNO line(s) have been detected, fall in a fairly narrow range of about 20 – 60.

Cyanic acid, HOCN, was identified tentatively in two previously published line surveys of Sgr B2(OH) and in one unpublished survey of the same source:
S. Brünken, C. A. Gottlieb, M. C. McCarthy, and P. Thaddeus,
Laboratory Detection of HOCN and Tentative Identification in Sgr B2
Astrophys. J. 697, (2009), 880.
The transitions detected were the Ka = 0, J = 4 – 3 and 5 – 4; the 5 – 4 and 6 – 5; and the 7 – 6. The firts two pairs of transitions have fairly similar intensities, the last, singly observed transition had not been calibrated. Even though the detection was deemed tentative, it is probably fairly secure.

More recently, the Sgr B2 region was studied more thoroughly by:
S. Brünken, A. Belloche, S. Martín, L. Verheyen, and K. M. Menten,
Interstellar HOCN in the Galactic Center Region
Astron. Astrophys. 516, (2010), Art. No. A109.
Data from a line survey of Sgr B2(M) and (N) were supllemented by dedicatedf searches toward several other positions in the Sgr B2 region. Up to four Ka = 0 transitions were detected with the IRAM 30 m telescope. The transitions had J" = 3, 4, 6, and 7 and extend from 83 to 168 GHz. Interestingly, they authours found a nearly contant HNCO/HOCN ratio of around 200. Moreover, the molecules were less abundant toward the hot and dense regions.

Contributor(s): H. S. P. Müller; 02, 2009; 05, 2009; 05, 2010; 03, 2012; 06, 2016